Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction
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Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction
A bimetallic heme-DNA cofactor, containing an iron and a copper center, was synthesized for the design of novel hybrid catalysts for stereoselective synthesis. The cofactor was used for the reconstitution of apo-myoglobin. Both the cofactor alone and its myoglobin adduct were used to catalyze a model Diels Alder reaction. Stereoselectivity of this conversion was analyzed by chiral HPLC. Reactio...
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ژورنال
عنوان ژورنال: Croatica Chemica Acta
سال: 2011
ISSN: 0011-1643,1334-417X
DOI: 10.5562/cca1828